Thaw pork chops in refrigerator overnight, remove from the refrigerator, and pat dry with paper towels.
Coat chops with 2 tablespoons grapeseed oil, then season liberally with rub all over; allow chops to come to room temperature for about 20 minutes.
Preheat oven to 400 degrees Fahrenheit.
In a large pan, add the remaining grapeseed oil and bring to medium-high heat.
Sear pork chops for about 2 minutes on each side, and sear the fat on each side of the chops about 30 seconds.
Remove chops from the pan and place on a wire rack-lined baking sheet.
Liberally baste pork chops with mustard glaze, reserving about 1/3 cup.
Cook pork chops in oven about 8 to 10 minutes until internal temperature reaches 140 degrees Fahrenheit as per a meat thermometer for medium doneness.
Rest chops for about 5 minutes until the internal temperature reaches 145 degrees as per a meat thermometer.
Sauce pork chops with reserved mustard glaze and serve with steakhouse potatoes.